number |
section |
caption |
|
Spin States |
Graphical relationship between field Bo and frequency . |
|
Spin States |
Creation of the Be field by the circulation of electrons in response to the Bo field. Be opposes Bo at the nucleus. |
|
Chemical Shift |
Tetramethylsilane (TMS). |
|
Chemical Shift |
NMR chart papers for 1H and 13C NMR. |
|
Chemical Shift |
The 1H NMR spectrum of methyl acetate. |
|
Chemical Shifts (Proton) |
The effect of electronegative elements on chemical shift. |
|
Chemical Shifts (Proton) |
Components of the Be field produced by the circulation of -electrons in alkenes, aromatics, and alkynes as a function of orientation relative to the applied field Bo. The major anisotropic contribution to the total Be field from circulation of -electrons adds to (alkene or aromatic) or subtracts from Bo (alkyne). |
|
Chemical Shifts (Proton) |
Approximate proton chemical shifts. |
|
Chemical Shifts (Carbon) |
Comparison of carbon chemical shifts and proton chemical shifts calculated using empirical rules and ChemDraw software. |
|
Chemical Shifts (Carbon) |
1H and 13C NMR spectra of 1-bromobutane. |
|
Chemical Shifts (Carbon) |
Carbon shift values for t-butyl benzene. |
|
Energy absorbtion |
Precessing spin vectors. |
|
Energy absorbtion |
The 6 NMR-equivalent protons of acetone. |
|
Energy absorbtion |
Vector diagram illustrating the NMR experiment. |
|
Energy absorbtion |
1H frequency and time domain spectra of 1-methoxy-2-propanone in CDCl3. |
|
Coupling (proton) |
Splitting of an NMR signal into a doublet as a result of the Bn field produced by a single vicinal proton. |
|
Coupling (proton) |
Splitting of an NMR signal into a triplet as a result of the Bn field produced by two vicinal protons. |
|
Coupling (proton) |
Splitting of an NMR signal into a quartet as a result of the Bn field produced by three vicinal protons. |
|
Coupling (proton) |
Pascal's Triangle. |
|
Coupling (proton) |
Examples of proton-proton coupling constants (J) as a function of structure. |
|
Coupling (proton) |
Examples of diastereotopic hydrogens. |
|
Coupling (proton) |
1H NMR spectrum of methyl propanoate. |
|
Complex splitting |
1H NMR spectrum of phenyloxirane showing the AMX pattern of three doublets of doublets. |
|
Complex splitting |
Second order intensity perturbation. |
|
Complex splitting |
1H NMR spectrum of 2-butanone showing tilted patterns of coupled protons. |
|
Coupling (carbon) |
Proton decoupled 13C spectrum of ethyl acetate in CDCl3. |
|
Integration (proton) |
Integration values for the 1H NMR spectrum of 2-butanone. |